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PREFACE
In offering this book to teachers of elementary chemistry the authors lay no claim to any great originality. It has been their aim to prepare a text-book constructed along lines which have become recognized as best suited to an elementary treatment of the subject. At the same time they have made a consistent effort to make the text clear in outline, simple in style and language, conservatively modern in point of view, and thoroughly teachable.
The question as to what shall be included in an elementary text on chemistry is perhaps the most perplexing one which an author must answer. While an enthusiastic chemist with a broad understanding of the science is very apt to go beyond the capacity of the elementary student, the authors of this text, after an experience of many years, cannot help believing that the tendency has been rather in the other direction. In many texts no mention at all is made of fundamental laws of chemical action because their complete presentation is quite beyond the comprehension of the student, whereas in many cases it is possible to present the essential features of these laws in a way that will be of real assistance in the understanding of the science. For example, it is a difficult matter to deduce the law of mass action in any very simple way; yet the elementary student can readily comprehend that reactions are reversible, and that the point of equilibrium depends upon, rather simple conditions. The authors believe that it is worth while to present such principles in even an elementary and partial manner because they are of great assistance to the general student, and because they make a foundation upon which the student who continues his studies to more advanced courses can securely build.
The authors have no apologies to make for the extent to which they have made use of the theory of electrolytic dissociation. It is inevitable that in any rapidly developing science there will be differences of opinion in regard to the value of certain theories. There can be no question, however, that the outline of the theory of dissociation here presented is in accord with the views of the very great majority of the chemists of the present time. Moreover, its introduction to the extent to which the authors have presented it simplifies rather than increases the difficulties with which the development of the principles of the science is attended.
Table of contents (by pages)
- 1: An Elementary Study of Chemistry by Henderson
- 2: William Lloyd Evans of this laboratory
- 3: Neutralization 106 xi
- 4: Intimate relation of chemistry and physics
- 5: Physical and chemical properties
- 6: The mixture tastes just like salt
- 7: The liquid called carbon disulphide
- 8: Nitrogen means the producer of niter
- 9: Chemical affinity the cause of chemical combination
- 10: Preparation from potassium chlorate usual laboratory method
- 11: 4 Directions for preparing oxygen
- 12: If the oxidation takes place rapidly
- 13: Phlogiston theory of combustion
- 14: 3 volumes of oxygen forming 2 volumes of ozone
- 15: Allotropic states or forms of matter
- 16: In a laboratory where the barometric reading is 740 mm
- 17: Representing the pressure of the aqueous vapor by a
- 18: Of potassium chlorate and 25 g
- 19: Setting free the hydrogen
- 20: The resulting compound contains zinc
- 21: The combustion of the hydrogen is
- 22: While hydrogen is readily combustible
- 23: While the oxyhydrogen flame is intensely hot
- 24: It may be either qualitative or quantitative
- 25: The method may be made quantitative
- 26: A more convenient form of eudiometer
- 27: 21 Method used by Berzelius and Dumas
- 28: The mineral analysis of a water is
- 29: Large filtration beds are prepared from sand and gravel
- 30: Such substances are said to be deliquescent
- 31: Since the pure dioxide is explosive
- 32: Of the ordinary hydrogen dioxide solution
- 33: Carbon and oxygen combine in two different ratios
- 34: Independent particles which Dalton designated as atoms
- 35: One atom of one with one atom of another
- 36: The molecules of which contain 2 atoms of hydrogen
- 37: When water is electrolyzed two new substances
- 38: Having the composition represented by the formula ZnSO 4
- 39: Of 1 zinc atom to 2 hydrogen atoms
- 40: Thus the formula for crystallized copper sulphate is CuSO 4
- 41: Of common hydrogen dioxide solution
- 42: And Lavoisier gave it the name azote
- 43: To which they gave the name argon
- 44: And xenon have been obtained from liquid air
- 45: Carbon dioxide and water vapor
- 46: Plus twice this volume of hydrogen
- 47: Determination of carbon dioxide
- 48: 00% Carbon dioxide 0
- 49: It can be liquefied by the same methods
- 50: Gradually followed by the oxygen
- 51: Circumstances affecting the solubility of gases
- 52: Calcium chloride 49
- 53: Such a solution is said to be supersaturated
- 54: The theory of electrolytic dissociation and electrolysis
- 55: Electrolysis of sodium chloride
- 56: Nitric acid is a liquid composed of hydrogen
- 57: Since all bases produce hydroxyl anions
- 58: 34 and the sodium hydroxide in the other
- 59: Do all the molecules dissociate into ions
- 60: The anion of sulphuric acid and calcium sulphate
- 61: Example sodium chloride NaCl
- 62: Combine with other univalent elements
- 63: If a trivalent element combines with a divalent element
- 64: And aluminium have valences of 1
- 65: COMPOUNDS OF NITROGEN WITH HYDROGEN Ammonia NH 3
- 66: NH 4 Cl NaOH NaCl NH 4 OH
- 67: 36 Ammonium hydroxide NH 4 OH
- 68: 37 Preparation of nitric acid
- 69: If carbon is oxidized by nitric acid
- 70: N 2 O 3 nitrogen trioxide
- 71: Yielding water and nitrogen trioxide
- 72: Ammonium hydroxide is a weak base
- 73: Producing iron oxide and hydrogen
- 74: And the undissociated molecules
- 75: Two different ions may form undissociated molecules
- 76: Rhombic sulphur and monoclinic sulphur
- 77: Hydrosulphuric acid is a weak acid
- 78: The salts of hydrosulphuric acid
- 79: 1 Na 2 SO 3 2HCl 2NaCl H 2 SO 3
- 80: Properties of sulphur trioxide
- 81: The catalyzers most used are platinum powder
- 82: Together with air and some nitrogen peroxide
- 83: Thiosulphuric acid H 2 S 2 O 3
- 84: The three acids of sulphur are dibasic acids
- 85: Crystallize in two different systems
- 86: Of hydrosulphuric acid were liberated
- 87: The arrangement suggested by Mendeleeff
- 88: It is placed just under lithium
- 89: But fluorine is an element of small atomic weight
- 90: In like manner the formulas RH
- 91: Fluorine belongs with chlorine and not with manganese
- 92: Fluorine does not form any oxides
- 93: This is the well known mineral fluorspar
- 94: MnO 2 with concentrated hydrochloric acid
- 95: Chlorine has a strong affinity for hydrogen
- 96: Hydrochloric acid muriatic acid HCl
- 97: CuO 2HCl CuCl 2 H 2 O
- 98: Since hydrobromic acid is not an article of commerce
- 99: Preparation of pure hydrobromic acid
- 100: Chlorine acts upon both bromides and free hydrobromic acid
- 101: More unstable than either hydrochloric or hydrobromic acids
- 102: A solution of hydriodic acid on standing turns brown
- 103: While graphite and coal are largely carbon
- 104: Pure amorphous carbon is best prepared by charring sugar
- 105: While lampblack is used for indelible inks
- 106: Regarding it as sodium hydroxide alone
- 107: This escapes through the stopcock
- 108: Carbon dioxide is incombustible
- 109: Which contains large amounts of carbon monoxide
- 110: Hydrocyanic acid prussic acid HCN
- 111: Are lampblack and bone black allotropic forms of carbon
- 112: The coal gas supporting the combustion
- 113: In general the hotter the flame the greater the luminosity
- 114: Such as hydrogen sulphide and ammonia
- 115: But is composed principally of methane
- 116: Are filled into the furnace up to the electrodes
- 117: Determination of atomic weights
- 118: In barium dioxide the proportion is 16 g
- 119: The oxygen molecule contains two atoms
- 120: 9046 to make the comparison with oxygen molecules
- 121: Molecular weights of the elements
- 122: 3% O was found to have a molecular weight of 98
- 123: The molecular weight of ammonia is 17
- 124: And antimony the oxides are acid anhydrides
- 125: Calcium phosphate is a constituent of all fertile soil
- 126: The phosphonium salts are of but little importance
- 127: The orthophosphates form an important class of salts
- 128: Or by heating the arsenopyrite in iron tubes
- 129: Arsine is a gas with a peculiar garlic like odor
- 130: H 3 AsO 4 orthoarsenic acid
- 131: Though the mineral stibnite is black
- 132: Bismuth has almost no acid properties
- 133: Conditions favoring hydrolysis
- 134: In the preparation of phosphine
- 135: Which is a silicide of carbon of the formula CSi
- 136: Metasilicic acid when heated breaks up into silica and water
- 137: In fused sodium or potassium silicate
- 138: And in salts of polyboric acids
- 139: While the metallic element forms the cations
- 140: Hence it is sometimes called the Goldschmidt method
- 141: Thus barium sulphate is not soluble in water
- 142: All sulphates are soluble save those of barium
- 143: Univalent metallic ions which are colorless
- 144: And calcium by means of electrolysis
- 145: Forming melted sodium hydroxide and hydrogen
- 146: Sodium sulphate forms large efflorescent crystals
- 147: The prefix thio means sulphur
- 148: As shown in the first equation under the Solvay process
- 149: Sodium phosphate Na 2 HPO 4
- 150: While disodium phosphate is nearly neutral in reaction
- 151: This changes the bromate to bromide
- 152: Leaving potassium nitrate in solution
- 153: And the acid sulphite KHSO 3
- 154: As well as the acid carbonate NH 4 HCO 3
- 155: Rubidium and caesium were discovered in this way
- 156: Between sodium chloride and ammonium chloride
- 157: Forming calcium hydroxide and hydrogen
- 158: Forming the carbonate CaO CO 2 CaCO 3
- 159: Marble when pure is made up of minute calcite crystals
- 160: Calcium fluoride fluorspar CaF 2
- 161: Calcium sulphate gypsum CaSO 4
- 162: Though celestite is sometimes colored a faint blue
- 163: Soluble barium compounds are poisonous
- 164: Caves often occur in limestone
- 165: Magnesium hydroxide Mg OH 2
- 166: Magnesium carbonate is insoluble in water
- 167: To hydrolysis of magnesium salts
- 168: Zinc oxide zinc white ZnO
- 169: Some of the chloride is decomposed ZnCl 2
- 170: Being heavier than cryolite
- 171: Consisting of about 90% copper and 10% aluminium
- 172: Aluminium hydroxide Al OH 3
- 173: Though they contain no aluminium
- 174: It instantly begins to hydrolyze
- 175: Supposing bauxite to be 90% aluminium hydroxide
- 176: While cobalt salts are usually rose colored
- 177: The tuyers are supplied from a large pipe S
- 178: The ferromanganese may contain as much as 80% manganese
- 179: The silicon first and then the carbon
- 180: 5% carbon is characterized by the property of taking temper
- 181: It can also act as a trivalent metal
- 182: They hydrolyze even more readily than the salts of aluminium
- 183: The same equation may be written 2Fe
- 184: When added to a solution of a ferric salt
- 185: Being always a univalent metal
- 186: The most important cuprous compound is the oxide Cu 2 O
- 187: Cupric sulphate blue vitriol CuSO 4
- 188: Mercurous chloride calomel HgCl
- 189: In the form of an alloy with zinc
- 190: Compounds of silver with the halogens
- 191: If the paper is coated with silver chloride
- 192: Called cassiterite or tinstone
- 193: Stannic chloride is formed SnCl 2 2Cl SnCl 4
- 194: Forming black lead sulphide PbS
- 195: What sulphates other than lead are insoluble
- 196: Manganese dioxide pyrolusite MnO 2
- 197: Manganous sulphate MnSO 4
- 198: Chromite is the ferrous salt of this acid
- 199: Chromic acid and dichromic acid
- 200: Oxidizing action of chromates and dichromates
- 201: What weight of the permanganate was required
- 202: And iridium are the heaviest substances known
- 203: Forming platinic chloride PtCl 4
- 204: It may be refined by cupellation
- 205: Forming gold chloride AuCl 3
- 206: The methane series is the most extensive
- 207: Properties of the hydrocarbons
- 208: Which is partially filled with limewater
- 209: 08 per gallon on the 94% product
- 210: CHO 2 formic acid
- 211: The free palmitic and stearic acids are precipitated
- 212: Palmitin and stearin are solids
- 213: This process is known as saponification
- 214: Levulose C 6 H 12 O 6
- 215: Dextrose and levulose are also isomeric
- 216: The product C 6 H 5 NO 2 is called nitrobenzene
- 217: An Elementary Study of Chemistry by Henderson
- 218: 6
- 219: Definition 4Chili saltpeter 191
- 220: 328Crystallization 98 water of 54
- 221: 335Fermentation 404 acetic 406 alcoholic 404
- 222: Table 220Gasoline 400German silver 323
- 223: 347 wrought 343 Jasper 260 Kainite 288Kaolin 261
- 224: 399Methylamine 412Mexican onyx 305Mica 261
- 225: 14
- 226: An Elementary Study of Chemistry by Henderson
- 227: An Elementary Study of Chemistry by Henderson
- 228: 264Topaz 331Triad families 166Tungsten 388Type metal 253
- 229: Professor of Chemistry in Ohio State University
- 230: Associate Professor of Physics
- 231: 7617 Carbon dioxide 1
